Issue 10, 2011
From the journal:

Nanoscale

6.5% efficient perovskite quantum-dot-sensitized solar cell†

Jeong-Hyeok Im,a   Chang-Ryul Lee,a   Jin-Wook Lee,a   Sang-Won Parka  and  Nam-Gyu Park*a  

* Corresponding authors

a School of Chemical Engineering and Department of Energy Science, Sungkyunkwan University, Suwon, Korea
E-mail: npark@skku.edu
Fax: +82-31-290-7272
Tel: +82-31-290-7241

Abstract

Highly efficient quantum-dot-sensitized solar cell is fabricated using ca. 2–3 nm sized perovskite (CH3NH3)PbI3 nanocrystal. Spin-coating of the equimolar mixture of CH3NH3I and PbI2 in γ-butyrolactone solution (perovskite precursor solution) leads to (CH3NH3)PbI3 quantum dots (QDs) on nanocrystalline TiO2 surface. By electrochemical junction with iodide/iodine based redox electrolyte, perovskite QD-sensitized 3.6 μm-thick TiO2 film shows maximum external quantum efficiency (EQE) of 78.6% at 530 nm and solar-to-electrical conversion efficiency of 6.54% at AM 1.5G 1 sun intensity (100 mW cm−2), which is by far the highest efficiency among the reported inorganic quantum dot sensitizers.

Graphical abstract: 6.5% efficient perovskite quantum-dot-sensitized solar cell

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Article information

DOI
https://doi.org/10.1039/C1NR10867K
Article type
Communication
Submitted
19 júl. 2011
Accepted
15 ágú. 2011
First published
07 sep. 2011

Nanoscale, 2011,3, 4088-4093

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6.5% efficient perovskite quantum-dot-sensitized solar cell

J. Im, C. Lee, J. Lee, S. Park and N. Park, Nanoscale, 2011, 3, 4088 DOI: 10.1039/C1NR10867K

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