Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

Masaichi Saito; Naoki Matsunaga; Jumpei Hamada; Shunsuke Furukawa; Mao Minoura; Susann Wegner; Juri Barthel; Christoph Janiak

doi:10.1039/C8DT01455H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand†‡

Masaichi Saito,

*^a Naoki Matsunaga,^a Jumpei Hamada,^a Shunsuke Furukawa,

^a Mao Minoura,^b Susann Wegner,^c Juri Barthel

^d and Christoph Janiak

Author affiliations

* Corresponding authors

^a Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo, Sakura-ku, Saitama-city, Saitama, Japan
E-mail: masaichi@chem.saitama-u.ac.jp

^b Department of Chemistry, College of Science, Rikkyo University, Nishi-ikebukuro, Toshima-ku, Tokyo, Japan

^c Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstr. 1, D-40225 Düsseldorf, Germany

^d Gemeinschaftslabor für Elektronenmikroskopie RWTH-Aachen, Ernst Ruska-Centrum für Mikroskopie und Spektroskopie mit Elektronen, Forschungszentrum Jülich GmbH, D-52425 Jülich, Germany

Abstract

A neutral heterobimetallic triple-decker stannole complex was prepared by the reaction of an anionic ruthenocene bearing a stannole dianionic ligand with [Rh(cod)Cl]₂ (cod = 1,5-cyclooctadiene), and the resulting Ru–Rh complex exhibits an electronic property different from those of the corresponding Ru–Ru and Rh–Rh complexes. The Ru–Rh complex can be decomposed in ionic liquids to metal nanoparticles.

This article is part of the themed collection: Philip Power at 65: an icon of organometallic chemistry

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C8DT01455H
Article type: Paper
Submitted: 13 apr. 2018
Accepted: 07 maí 2018
First published: 10 maí 2018

Download Citation

Dalton Trans., 2018,47, 8892-8896

Permissions

Request permissions

Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

M. Saito, N. Matsunaga, J. Hamada, S. Furukawa, M. Minoura, S. Wegner, J. Barthel and C. Janiak, Dalton Trans., 2018, 47, 8892 DOI: 10.1039/C8DT01455H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions

Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand†‡

Abstract

Supplementary files

Article information

Download Citation

Permissions

Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

Social activity

Search articles by author

Spotlight

Advertisements