Two new approaches to the functionalization of the 1-carba-closo-decaborate anion [1-CB9H10]− at boron atoms via the ring-opening of its 1,4-dioxane derivative with various nucleophiles and Pd-catalysed cross-coupling of its iodo derivative with aromatic amines and heteroaromatics were developed.
A. V. Shmal’ko, P. Cendoya, S. A. Anufriev, K. Yu. Suponitsky, D. Gabel and I. B. Sivaev, Chem. Commun., 2022, 58, 3775 DOI: 10.1039/D1CC06395B
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