Themed collection Professor Edward Abel Honorary Collection
Professor Edward Abel, FRSC, CBE (1931–2021)
In honour of Eddie (Ed) Abel, past president of the Royal Society of Chemistry, who passed away on April 19, 2021, at 89.
Dalton Trans., 2022,51, 16781-16783
https://doi.org/10.1039/D2DT90160A
Metallomesogens by ligand design
Columnar phases can be realised when basic salicylaldimine complexes are modified in the appropriate way. This Perspective discusses how control such as this may be exercised.
Dalton Trans., 2003, 1914-1931
https://doi.org/10.1039/B212610A
Anion recognition by halogen bonding and hydrogen bonding bis(triazole)-imidazolium [2]rotaxanes
A novel halogen bonding bis(iodotriazole)-imidazolium axle containing [2]rotaxane is capable of strong halide and sulfate binding in highly competitive aqueous–organic solvent mixtures.
Dalton Trans., 2021,50, 12800-12805
https://doi.org/10.1039/D1DT02414K
Synthetic, spectroscopic, computational and structural studies of some 13-vertex ruthenacarboranes
Thirteen-vertex ruthenacarboranes with 4,1,6-RuC2B10 architectures are fluctional in solution at room temperature via a double diamond–square–diamond process whose activation barrier has been estimated both computationally and experimentally.
Dalton Trans., 2005, 1716-1721
https://doi.org/10.1039/B500944H
Dynamic nuclear magnetic resonance study of the effects of cis-chelate ligands on 1,2-metallotropic shifts in trimethylplatinum(IV) complexes of pyridazine
2,2′:6′,2″-Terpyridine (terpy) acting as a fluxional bidentate ligand. Part 4. cis-[M(C6F5)2(terpy)](M = Pd or Pt): nuclear magnetic resonance studies of their solution dynamics and crystal structure of cis-[Pd(C6F5)2(terpy)]
1,2-Metallotropic shifts in trimethylplatinum(IV) and tricarbonylrhenium(I) halide complexes of pyridazine and 4-methylpyridazine
Platinum and rhodium complexes of dialkenyl telluroether ligands: synthesis, dynamic nuclear magnetic resonance and crystal structure of cis-dibromo(3,3,7,7-tetramethyl-5-tellura-3,7-disilanona-1,8-diene)platinum(II)
2,2′:6′,2″-Terpyridine (terpy) acting as a fluxional bidentate ligand. Part 2. Rhenium carbonyl halide complexes, fac-[ReX(CO)3(terpy)](X = Cl, Br or I): NMR studies of their solution dynamics, synthesis of cis-[ReBr(CO)2(terpy)] and the crystal structure of [ReBr(CO)3(terpy)]
2,2′:6′,2″-Terpyridine (terpy) acting as a fluxional bidentate ligand. Part 1. Trimethylplatinum(IV) halide complexes [PtXMe3(terpy)](X = Cl, Br or I): nuclear magnetic resonance studies of their solution dynamics and crystal structure of [PtIMe3(terpy)]
Halogenotrimethylplatinum(IV) complexes of 2,6-bis(p-tolylthiomethyl)pyridine (L1): nuclear magnetic resonance studies of their solution state stereodynamics and the crystal structure of fac-[PtBrMe3L1]
Synthesis and crystal structure of 1,1′,2,2′-bis(1,2,3-trithia-[3])ferrocenophane
Nuclear magnetic resonance investigations of a novel intramolecular methylthio replacement process in palladium(II) and platinum(II) complexes of mixed sulfur–phosphine ligands
Halogenotricarbonylrhenium(I) complexes of 2,6-bis(thioalkyl)- and -(thioaryl)-pyridines, their syntheses and solution stereodynamics
A dynamic nuclear magnetic resonance study of trimethylplatinum(IV) halide complexes of 1,1,2,2-tetrakis(methylthio)ethane. Part 3. Structure and fluxionality of dinuclear complexes [(PtXMe3)2{(MeS)2CHCH(SMe)2}]
Platinum metal complexes of potentially chelating alkene–sulphur and alkene–selenium ligands. The synthesis by chalcogen dealkylation and X-ray structures of the dimeric complexes [{PtI(SCH2CH2CMeCH2)}2] and [{PtI(PPh3)(SCH2CH2CMeCH2)}2], and a dynamic nuclear magnetic resonance study of [{PtI(L)(SCH2CH2CMeCH2)}2][L = PPh3, PPh2Me, or As(CH2SiMe3)3]
Some transition-metal complexes of 1,3,2-dithiarsolane
A dynamic nuclear magnetic resonance study of trimethylplatinum(IV) halide complexes of 1,1,2,2- tetrakis(methylthio)ethane. Part 2. High-temperature fluxionality
Platinum metal complexes of potentially chelating alkene–thioether and alkene–selenoether ligands: synthesis and dynamic nuclear magnetic resonance study of [MX2{MeE(CH2)nCHCH2}](M = Pt or Pd; X = Cl, Br, or I; E = S or Se; n= 2 or 3) and the X-ray structure of cis-dibromo(2-thia-6-heptene)platinum(II), [PtBr2{{MeS(CH2)3CHCH2}]
A dynamic nuclear magnetic resonance study of trimethylplatinum(IV) halide complexes of 1,1,2,2-tetrakis(methylthio)ethane. Part 1. Low-temperature solution properties, and X-ray crystal structure of [PtlMe3{(MeS)2CHCH(SMe)2}]
Platinum metal complexes of potentially chelating alkene thioether and selenoether ligands: the synthesis and dynamic nuclear magnetic resonance study of [MX2{E[(CH2)nCRCR2]2}](M = Pt or Pd; X = Cl, Br, or I; E = S or Se; n= 2 or 3; R = H or Me) and the X-ray crystal structure of cis-di-iodo-(5-thianona-1,8-diene)platinum(II), [PtI2{S[(CH2)2CHCH2]2}]
Stereochemical non-rigidity of dithioether complexes of trimethylplatinum(IV) halides. X-Ray crystal structures of [PtClMe3(MeSCH2CH2SEt)] and [PtIMe3(MeSCH2CH2SBut)]
Sulphur–arsenic ligands. Dimethyl(methylthio)arsine complexes of halogenotrimethylplatinum(IV) and tricarbonylhalogenorhenium(I)
Heteronuclear 1,3-intramolecular metal shifts in pentacarbonyl-chromium, -molybdenum, and -tungsten derivatives of 2-thia-4-selenapentane. A dynamic nuclear magnetic resonance investigation
Pyramidal inversions and 1,2-metal shifts in pentacarbonyl-chromium, -molybdenum, and -tungsten derivatives of dialkyl disulphides and dialkyl diselenides. A nuclear magnetic resonance investigation
A nuclear magnetic resonance study of pyramidal atomic inversion in complexes of tricarbonylrhenium(I) halides with saturated and unsaturated thio- and seleno-ethers: an X-ray crystal structure of [Rel(CO)3{MeSe(CH2)2SeMe}]
Nuclear magnetic resonance study of pyramidal inversion and intramolecular rearrangements in complexes of trimethylplatinum(IV) halides with aliphatic and aromatic mixed thio–seleno-ethers
Nuclear magnetic resonance investigations of configurational non-rigidity in dinuclear platinum(IV) complexes. Part 4. Ring reversal, pyramidal inversion, and novel fluxional rearrangements in [(PtXMe3)2(MeSCH2SeMe)] complexes
Terminal and bridged phosphole, arsole, and stibole complexes of molybdenum, tungsten, manganese, rhenium, and iron
Syntheses of nonacarbonylbis(µ3-ethoxy)(µ2-halogeno)trimanganese complexes, the crystal structures of the fluoride and iodide, and the crystal structure of octacarbonyl(dimethylphenylphosphine)bis(µ3-ethoxy)(µ2-ethoxy)trimanganese
η-Tetraphenylphospholyl and η-tetraphenylarsolyl derivatives of manganese, rhenium, and iron
Syntheses, structures, and reactions of trimeric and tetrameric alkoxotricarbonylmanganese complexes
Effect of variation in ligand ring size upon the inversion barrier at sulphur in complexes of palladium(II) and platinum(II). A dynamic hydrogen-1 nuclear magnetic resonance study
Silacyclopentadiene complexes of molybdenum, chromium, iron, ruthenium, cobalt, and rhodium
The association of cobalt(II) tetrasulphophthalocyanine
Syntheses and properties of aminomethyl complexes of manganese and rhenium
Organotin reagents for the synthesis of π-allyl, π-cyclopentadienyl, π-indenyl, and other related π-enyl carbonyl derivatives of the transition metals
The 1,4-insertion reactions of 1,1-bis(perhalogenomethyl)-2,2-dicyanoethylenes to produce ketenimines
About this collection
This collection of papers honours Professor Eddie (Ed) Abel, past President of the Royal Society of Chemistry. The collection comes primarily from J. Chem. Soc., Dalton Trans. (and latterly Dalton Trans.) plus a couple of important Chemical Communication papers, and have been chosen by former colleagues of Ed with a personal connection to the research or papers that have been inspired by his legacy. They demonstrate the breadth of his scientific interests and are taken from various stages of his independent career. Thank you Ed for your passion and inspiration for inorganic and organometallic chemistry!