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New aggregation-induced emission (AIE) luminogens with high solid-state emission efficiencies are developed by adopting a benzo[b]thiophene S,S-dioxide core, and steric and electronic effects on the AIE property are elucidated.

Graphical abstract: A novel aggregation-induced emission platform from 2,3-diphenylbenzo[b]thiophene S,S-dioxide

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