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All-inorganic Pb–Cd mixed-cation halide perovskites have emerged as semiconductors exhibiting improved optical and optoelectronic properties. We establish a reliable correlation between photoluminescence and Cd content x in bulk CsPb1−xCdxBr3 compositions, propose pathways of photoexcited charge carrier dynamics in them, and show improved stability of lasing in whispering gallery mode microdisks.

Graphical abstract: Composition tunable and stable spontaneous emission and lasing in Cd-alloyed perovskite microdisks

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