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Graphene grown on Ir(111) electronically decouples adsorbed molecules from the metallic substrate and allows the study of their self-organization on surfaces. We study two electron acceptor molecules from the same family. The intermolecular interaction, attractive for TCNQ and repulsive for F4-TCNQ, dictates the molecular ordering.

Graphical abstract: Self-organization of electron acceptor molecules on graphene

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