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Abstract | Cited by

We develop novel membrane electrolytes comprising h-BN-doped poly(ethylene oxide) modified poly(vinylidene fluoride-co-hexafluoropropylene)-nanofibers (h-BN@PEO/PVH) with high ionic conductivity (3.3 × 10−4 S cm−1) and Li+ transference number (0.74), endowing solid LiFePO4//Li batteries with excellent cyclability over 1000 cycles at 60 °C. Our strategy surmounts the ionic conduction-interface stability trade-off and thin dimension-flexibility conflict.

Graphical abstract: A ternary composite nanofiber-derived thin membrane electrolyte for solid-state Li metal batteries

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