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Presence of strongly binding anion, F stabilizes the photo-induced charge-separated states of a bis-fullerene-substituted oxoporphyrinogen due to the large shift in the oxidation potential of the oxoporphyrinogen moiety upon anion binding through hydrogen bonding at its core.

Graphical abstract: Effect of anion binding on charge stabilization in a bis-fullerene–oxoporphyrinogen conjugate

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