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Fullerenes are generally considered as highly symmetric, yet fullerene isomers with only C1 symmetry, such as C1(30)–C90 and C1(32)–C90 whose structures are reported here, become increasingly numerous as fullerene size increases.

Graphical abstract: Fullerenes without symmetry: crystallographic characterization of C1(30)–C90 and C1(32)–C90

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