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A tetraphenylethene-based Pd2L4 metallacage was self-assembled from four TPE-pyridine ligands with two Pd2+ ions. This metallacage with D4 symmetry exhibited a classical aggregation-induced emission property in different solvents and reversible stimuli-responsive behaviour with chloride ions and silver ions, successively.

Graphical abstract: A tetraphenylethene-based Pd2L4 metallacage with aggregation-induced emission and stimuli-responsive behavior

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