Themed collection Most popular articles from National University of Singapore

Revolutionary SAMs: transforming inverted perovskite solar cells
Revolutionary self-assembled monolayers, represented by xPACz, have propelled the rapid improvement in the performance of inverted perovskite solar cells.
J. Mater. Chem. A, 2024,12, 9929-9932
https://doi.org/10.1039/D4TA00962B
Progressing thin-film membrane designs for post-combustion CO2 capture: performance or practicality?
Thin-film composite membranes demonstrate tremendous potential for energy-efficient CO2 capture from power generation, but many technical hurdles are to be overcome before practical, better-performing and cost-effective designs could be realized.
J. Mater. Chem. A, 2023,11, 17452-17478
https://doi.org/10.1039/D3TA02842A

Advancing neodymium permanent magnets with laser powder bed fusion technology: a comprehensive review of process–structure–property relationship
This comprehensive review delves into the critical relationship between process, structure, and properties in the context of manufacturing neodymium (NdFeB) permanent magnets using laser powder bed fusion (LPBF) technology.
Mater. Adv., 2024,5, 8755-8771
https://doi.org/10.1039/D4MA00341A
Hydrogels: a promising therapeutic platform for inflammatory skin diseases treatment
Hydrogels revolutionize treating chronic skin diseases by enhancing drug delivery and reducing side effects. This review explores hydrogel design, drug integration, and clinical trials, highlighting their potential to improve efficacy and safety.
J. Mater. Chem. B, 2024,12, 8007-8032
https://doi.org/10.1039/D4TB00887A

PEDOT:PSS materials for optoelectronics, thermoelectrics, and flexible and stretchable electronics
Cutting-edge approaches to prepare PEDOT:PSS films/electrodes, significant progress on related devices are summarized; advantages, plausible questions, challenges, and suggestions are also presented for the continued development of modern electronics.
J. Mater. Chem. A, 2023,11, 18561-18591
https://doi.org/10.1039/D3TA03213B
Melanin: insights into structure, analysis, and biological activities for future development
A comprehensive review of melanin's structure, identification methods, and biological activities, highlighting its potential for further development and diverse applications in various fields.
J. Mater. Chem. B, 2023,11, 7528-7543
https://doi.org/10.1039/D3TB01132A

Carbon-centered radical based dynamic covalent chemistry for stimuli-responsive chromic materials
Stimuli-responsive chromic materials have received increasing research attention. This review summarizes the most cutting-edge carbon-centered radicals, with a focus on their structures, properties and applications as stimuli-chromic materials.
J. Mater. Chem. C, 2023,11, 7957-7969
https://doi.org/10.1039/D3TC00117B
Halide perovskite quantum dots for photocatalytic CO2 reduction
This review focuses on halide perovskite quantum dots (QDs) for photocatalytic CO2 reduction, discussing the structures and properties of perovskite QDs, the mechanism for CO2 reduction, photocatalyst design, challenges and directions for future research.
J. Mater. Chem. A, 2023,11, 12482-12498
https://doi.org/10.1039/D2TA09521A

Advances in harvesting water and energy from ubiquitous atmospheric moisture
Sorbent-assisted AWH and moisture-enabled energy generation are reviewed in parallel to reveal the correlation between these two technologies.
J. Mater. Chem. A, 2023,11, 12456-12481
https://doi.org/10.1039/D2TA09552A

Recent development and emerging applications of robust biomimetic superhydrophobic wood
Schematic illustration for the development and emerging applications of biomimetic superhydrophobic wood, including a variety of preparation strategies, durability tests, and representative emerging applications.
J. Mater. Chem. A, 2023,11, 6772-6795
https://doi.org/10.1039/D2TA09828H
Two-step fabrication of COF membranes for efficient carbon capture
A two-step method to fabricate COF nanosheets is proposed, comprising framework assembly and functional group switching. Functionalized COF-316 membranes were fabricated and demonstrated excellent separation performance.
Mater. Horiz., 2023,10, 5016-5021
https://doi.org/10.1039/D3MH00981E
Wide-temperature-range multispectral camouflage enabled by orientation-gradient co-optimized microwave blackbody metastructure coupled with conformal MXene coating
An orientation-gradient co-optimized graded Gyroid-shellular (GGS) SiOC-based metastructure with conformal MXene coating (MXene@SiOC) is proposed to achieve wide-temperature-range microwave/infrared/1.06 μm-laser/visible-light-compatible camouflage.
Mater. Horiz., 2023,10, 3404-3415
https://doi.org/10.1039/D3MH00611E

Harnessing cavity dissipation for enhanced sound absorption in Helmholtz resonance metamaterials
Drastically enhanced sound absorption can be achieved in Helmholtz resonators by simply reshaping the cavity and bringing the cavity walls close to the pore.
Mater. Horiz., 2023,10, 2892-2903
https://doi.org/10.1039/D3MH00428G
Tumor-microenvironment-responsive poly-prodrug encapsulated semiconducting polymer nanosystem for phototherapy-boosted chemotherapy
Phototherapy-induced hypoxia boosts the chem-therapy of PEG-TPZ for enhanced theranostics.
Mater. Horiz., 2023,10, 3014-3023
https://doi.org/10.1039/D3MH00242J
Hexagonal boron nitride nanophotonics: a record-breaking material for the ultraviolet and visible spectral ranges
A global trend towards miniaturization and multiwavelength performance of nanophotonics drives research on novel phenomena as well as surveys for high-refractive index and strongly anisotropic materials and metasurfaces, where hBN has a central role.
Mater. Horiz., 2023,10, 2427-2435
https://doi.org/10.1039/D3MH00215B
Selective spectral absorption of nanofibers for color-preserving daytime radiative cooling
The color-preserving daytime radiative cooling can be achieved by selective spectral absorption of nanofibers.
Mater. Horiz., 2023,10, 2487-2495
https://doi.org/10.1039/D3MH00391D
Liquid-based cationic ligand engineering in one-dimensional bismuth bromide perovskites: A-site influence on scintillation properties
Low-dimensional bismuth-based hybrid organic–inorganic halide perovskites (Bi-HOIPs) are intriguing scintillating materials due to their anisotropic nature.
J. Mater. Chem. C, 2025,13, 9051-9060
https://doi.org/10.1039/D4TC04390A
How is CO2 hydrogenated to ethanol on metal–organic framework HKUST-1? Microscopic insights from density-functional theory calculations
Through DFT calculations, we quantitatively and explicitly elucidate the fundamental mechanism involved in CO2 hydrogenation to ethanol on HKUST-1.
J. Mater. Chem. A, 2025,13, 9064-9072
https://doi.org/10.1039/D4TA08052A
Enhanced three-photon absorption excited at near-infrared laser pulses and stability of MAPbBr3 quantum dots encapsulated in mesoporous single MOF-5 crystals
The composite material MAPbBr3@MOF-5 exhibits not only significantly enhanced stability but also superior nonlinear optical properties under near-infrared laser pulse excitation.
J. Mater. Chem. C, 2025,13, 5719-5724
https://doi.org/10.1039/D4TC05087H

High-throughput computation and machine learning screening of van der Waals heterostructures for Z-scheme photocatalysis
We identify 62 Z-scheme heterostructures with excellent photocatalytic performance from 11 935 hetero-bilayer structures using high-throughput calculations and machine learning.
J. Mater. Chem. A, 2025,13, 5649-5660
https://doi.org/10.1039/D4TA07683D
Highly conductive PANI/ATMP/AgNO3 composite hydrogel electrodes for all-hydrogel-state supercapacitors
Highly conductive PANI/ATMP/AgNO3 composite hydrogel electrodes for flexible high energy density supercapacitors.
J. Mater. Chem. A, 2025,13, 5238-5251
https://doi.org/10.1039/D4TA07437H
In vivo transplantation of intrahepatic cholangiocyte organoids with decellularized liver-derived hydrogels supports hepatic cellular proliferation and differentiation in chronic liver injury
Liver-based hydrogel transplanted hepatocyte and cholangiocyte organoids as an efficient cell source and therapy for renewal of hepatocytes, angiogenesis, restoration of hepatocyte functions and resolution of liver injury.
J. Mater. Chem. B, 2025,13, 918-928
https://doi.org/10.1039/D4TB01503G
In situ analysis of a boron-based catalytic electrode with trace platinum for efficient hydrogen evolution in a wide pH range
An efficient Pt-NiB@NF catalytic electrode is rapidly constructed by mild electroless plating and electroplating. It demonstrates long-term stability at industrial-scale current densities in neutral high-salt media and alkaline systems.
J. Mater. Chem. A, 2024,12, 33649-33660
https://doi.org/10.1039/D4TA05770H

Low CO2 mass transfer promotes methanol and formaldehyde electrosynthesis on cobalt phthalocyanine
The ratio (R) of the production rates of CH3OH and CO from electrocatalytic CO2 reduction on Co phthalocyanine is related to the average CO2 mass-transfer rate (ν) by a power function (R = 0.97ν−0.78).
J. Mater. Chem. A, 2024,12, 31547-31556
https://doi.org/10.1039/D4TA03531C

A cradle-to-cradle approach for successive upcycling of polyethylene to polymer electrolytes to organic acids
We demonstrate the post-synthetic conversion of polyethylene into functional polymer electrolytes for lithium-ion batteries. To avoid end-of-life polymer electrolytes contributing to polymer waste, we further upcycle them into useful organic acids.
J. Mater. Chem. A, 2024,12, 20947-20957
https://doi.org/10.1039/D4TA02178A

Competition between CH4 hydrate formation and phase separation in a wetted metal–organic framework MIL-101 at moderate subcooling: molecular insights into CH4 storage
Systematic molecular dynamics simulations reveal the competition between CH4 hydrate formation and phase separation of CH4 in a mesoporous metal–organic framework MIL-101 at moderate subcooling.
J. Mater. Chem. A, 2024,12, 4447-4459
https://doi.org/10.1039/D3TA06952D
All-inorganic copper-halide perovskites for large-Stokes shift and ten-nanosecond-emission scintillators
Demonstration of how rational design affects self-trapped emission characteristics and scintillation properties in mechanochemically synthesised caesium copper halide perovskites.
J. Mater. Chem. C, 2024,12, 2398-2409
https://doi.org/10.1039/D3TC03977C
Selective grafting of phosphorus onto Ti3C2Tx MXene enables a two-proton process and enhanced charge storage
Phosphorus atoms are selectively doped onto Ti3C2Tx MXene, leading to solely P–O doped species, which serve as new active sites to enable two-proton bonding/debonding process to boost charge storage ability of MXene.
J. Mater. Chem. A, 2024,12, 3449-3459
https://doi.org/10.1039/D3TA06032B
Enhanced moisture sorption through regulated MIL-101(Cr) synthesis and its integration onto heat exchangers
Through regulated and less toxic MIL-101(Cr) synthesis and superabsorbent polymeric binders, this work reports MIL-101(Cr)-coated heat exchangers with twice the water uptake of the silica gel-coated control towards energy-efficient cooling.
J. Mater. Chem. A, 2024,12, 824-839
https://doi.org/10.1039/D3TA05141B
Thermal conductivity of sliding bilayer h-BN and its manipulation with strain and layer confinement
The AC′ structure with B–B stacking exhibits a lower κ value due to the softer optical phonon modes. The strain further decreases κ by modulating the anharmonic phonon scattering.
J. Mater. Chem. C, 2023,11, 11082-11090
https://doi.org/10.1039/D3TC01531A
Flexible Bi2Te3/PEDOT nanowire sandwich-like films towards high-performance wearable cross-plane thermoelectric generator and temperature sensor array
Flexible Bi2Te3/PEDOT nanowire sandwich-like films with a zT of 0.27 were fabricated for cross-plane wearable thermoelectric generation and thermal mapping.
J. Mater. Chem. A, 2023,11, 16039-16048
https://doi.org/10.1039/D3TA02876C
Cellulose-complexing strategy induced surface regulation towards ultrahigh utilization rate of Zn
A cellulose-complexing strategy is developed for zinc electrolytes to achieve dendrite-free Zn anodes with ultrahigh Zn utilization rate, driving the development of a robust artificial SEI fabrication method via a dissolution–regeneration mechanism.
J. Mater. Chem. A, 2023,11, 14720-14727
https://doi.org/10.1039/D3TA02117C
Low-temperature pyrolysis enables FeNi3 nanoparticle implanted N-doped carbon nanosheets as an efficient bifunctional electrocatalyst for overall water splitting
The electrocatalyst FeNi3/NCS was prepared via the low-temperature pyrolysis of the melamine tube@FeNi-LDH heterostructure, which delivered impressive activity and stability towards water splitting with a low cell potential of 1.53 V at 10 mA cm−2.
J. Mater. Chem. A, 2023,11, 14015-14024
https://doi.org/10.1039/D3TA01819A
Local microenvironment tuning induces switching between electrochemical CO2 reduction pathways
We show that the pore size of the gas-diffusion layer used in electrochemical CO2 reduction affects CO2 mass transport. This directly influences the local reaction microenvironment, controlling the selectivity between CO and formate on Ag catalysts.
J. Mater. Chem. A, 2023,11, 13493-13501
https://doi.org/10.1039/D3TA02558F
Tunable properties and composition of ZnO films supported on metal surfaces
The composition, electronic structure, and chemical properties of ZnOxHy films can be engineered by the choice of underlying metal support.
J. Mater. Chem. A, 2023,11, 13665-13676
https://doi.org/10.1039/D3TA01940C
Side-chain engineering of self-doped conjugated polyelectrolytes for organic electrochemical transistors
Varied-length conjugated polyelectrolytes (2–5 methylene units) containing CPDT-alt-BT were synthesized to study the optical, electrochemical, and morphological properties. These were used in accumulation mode organic electrochemical transistors.
J. Mater. Chem. C, 2023,11, 8274-8283
https://doi.org/10.1039/D3TC00355H
Molten salt synthesis of a highly crystalline graphitic carbon nitride homojunction from a deep eutectic solvent for selective photocatalytic oxidation
A highly crystalline graphitic carbon nitride homojunction was synthesized by calcination of deep eutectic solvent precursors in NaCl/KCl molten salt media and exhibited excellent performance in selective photocatalytic oxidation.
J. Mater. Chem. A, 2023,11, 12342-12353
https://doi.org/10.1039/D3TA01460F
Low-voltage organic single-crystal field-effect transistors and inverters enabled by a solution processable high-k dielectric
Low-voltage OFETs with excellent mobility, steep subthreshold swing, and low operating voltage were achieved simultaneously based on a novel solution-processable high-k dielectric.
J. Mater. Chem. C, 2023,11, 6580-6587
https://doi.org/10.1039/D3TC00246B
Gelatin methacryloyl hydrogel as an injectable scaffold with multi-therapeutic effects to promote antimicrobial disinfection and angiogenesis for regenerative endodontics
Regenerative endodontics represents a paradigm shift in dental pulp therapy for necrotic young permanent teeth.
J. Mater. Chem. B, 2023,11, 3823-3835
https://doi.org/10.1039/D2TB02788G

Enhanced thermoelectric performance in Bi0.5Sb1.5Te3/SiC composites prepared by low-temperature liquid phase sintering
A low-temperature liquid phase sintering method combined with post heat treatment was employed to prepare p-type Bi0.5Sb1.5Te3/SiC composites with enhanced thermoelectric properties.
J. Mater. Chem. A, 2023,11, 8912-8921
https://doi.org/10.1039/D2TA09850D
MXene-decorated flexible Al2O3/TiO2 nanofibrous mats with self-adaptive stress dispersion towards multifunctional desalination
A flexible Al2O3/TiO2 nanofibrous mat with a 2.18 MPa tensile strength has been created by stress dispersion method for 2D and 3D evaporators. The evaporator has an ultrahigh solar-to-vapor efficiency of 116% and ensures 10 h without salt buildup.
J. Mater. Chem. A, 2023,11, 7422-7431
https://doi.org/10.1039/D2TA09488F
About this collection
To mark the visit of Deputy Editor Geraldine Hay to the National University of Singapore in July 2025, this web collection features recent popular articles published in Materials Horizons, Journal of Materials Chemistry A, Journal of Materials Chemistry B, Journal of Materials Chemistry C and Materials Advances by authors based in the National University of Singapore.
Congratulations to all of the authors whose articles have been featured!