Themed collection Most popular articles from National University of Singapore

41 items
Highlight

Revolutionary SAMs: transforming inverted perovskite solar cells

Revolutionary self-assembled monolayers, represented by xPACz, have propelled the rapid improvement in the performance of inverted perovskite solar cells.

Graphical abstract: Revolutionary SAMs: transforming inverted perovskite solar cells
Perspective

Progressing thin-film membrane designs for post-combustion CO2 capture: performance or practicality?

Thin-film composite membranes demonstrate tremendous potential for energy-efficient CO2 capture from power generation, but many technical hurdles are to be overcome before practical, better-performing and cost-effective designs could be realized.

Graphical abstract: Progressing thin-film membrane designs for post-combustion CO2 capture: performance or practicality?
Open Access Review Article

Advancing neodymium permanent magnets with laser powder bed fusion technology: a comprehensive review of process–structure–property relationship

This comprehensive review delves into the critical relationship between process, structure, and properties in the context of manufacturing neodymium (NdFeB) permanent magnets using laser powder bed fusion (LPBF) technology.

Graphical abstract: Advancing neodymium permanent magnets with laser powder bed fusion technology: a comprehensive review of process–structure–property relationship
Review Article

Hydrogels: a promising therapeutic platform for inflammatory skin diseases treatment

Hydrogels revolutionize treating chronic skin diseases by enhancing drug delivery and reducing side effects. This review explores hydrogel design, drug integration, and clinical trials, highlighting their potential to improve efficacy and safety.

Graphical abstract: Hydrogels: a promising therapeutic platform for inflammatory skin diseases treatment
Open Access Review Article

PEDOT:PSS materials for optoelectronics, thermoelectrics, and flexible and stretchable electronics

Cutting-edge approaches to prepare PEDOT:PSS films/electrodes, significant progress on related devices are summarized; advantages, plausible questions, challenges, and suggestions are also presented for the continued development of modern electronics.

Graphical abstract: PEDOT:PSS materials for optoelectronics, thermoelectrics, and flexible and stretchable electronics
Review Article

Melanin: insights into structure, analysis, and biological activities for future development

A comprehensive review of melanin's structure, identification methods, and biological activities, highlighting its potential for further development and diverse applications in various fields.

Graphical abstract: Melanin: insights into structure, analysis, and biological activities for future development
Open Access Review Article

Carbon-centered radical based dynamic covalent chemistry for stimuli-responsive chromic materials

Stimuli-responsive chromic materials have received increasing research attention. This review summarizes the most cutting-edge carbon-centered radicals, with a focus on their structures, properties and applications as stimuli-chromic materials.

Graphical abstract: Carbon-centered radical based dynamic covalent chemistry for stimuli-responsive chromic materials
Review Article

Halide perovskite quantum dots for photocatalytic CO2 reduction

This review focuses on halide perovskite quantum dots (QDs) for photocatalytic CO2 reduction, discussing the structures and properties of perovskite QDs, the mechanism for CO2 reduction, photocatalyst design, challenges and directions for future research.

Graphical abstract: Halide perovskite quantum dots for photocatalytic CO2 reduction
Open Access Review Article

Advances in harvesting water and energy from ubiquitous atmospheric moisture

Sorbent-assisted AWH and moisture-enabled energy generation are reviewed in parallel to reveal the correlation between these two technologies.

Graphical abstract: Advances in harvesting water and energy from ubiquitous atmospheric moisture
Open Access Review Article

Recent development and emerging applications of robust biomimetic superhydrophobic wood

Schematic illustration for the development and emerging applications of biomimetic superhydrophobic wood, including a variety of preparation strategies, durability tests, and representative emerging applications.

Graphical abstract: Recent development and emerging applications of robust biomimetic superhydrophobic wood
Communication

Two-step fabrication of COF membranes for efficient carbon capture

A two-step method to fabricate COF nanosheets is proposed, comprising framework assembly and functional group switching. Functionalized COF-316 membranes were fabricated and demonstrated excellent separation performance.

Graphical abstract: Two-step fabrication of COF membranes for efficient carbon capture
Communication

Wide-temperature-range multispectral camouflage enabled by orientation-gradient co-optimized microwave blackbody metastructure coupled with conformal MXene coating

An orientation-gradient co-optimized graded Gyroid-shellular (GGS) SiOC-based metastructure with conformal MXene coating (MXene@SiOC) is proposed to achieve wide-temperature-range microwave/infrared/1.06 μm-laser/visible-light-compatible camouflage.

Graphical abstract: Wide-temperature-range multispectral camouflage enabled by orientation-gradient co-optimized microwave blackbody metastructure coupled with conformal MXene coating
Open Access Communication

Harnessing cavity dissipation for enhanced sound absorption in Helmholtz resonance metamaterials

Drastically enhanced sound absorption can be achieved in Helmholtz resonators by simply reshaping the cavity and bringing the cavity walls close to the pore.

Graphical abstract: Harnessing cavity dissipation for enhanced sound absorption in Helmholtz resonance metamaterials
Communication

Tumor-microenvironment-responsive poly-prodrug encapsulated semiconducting polymer nanosystem for phototherapy-boosted chemotherapy

Phototherapy-induced hypoxia boosts the chem-therapy of PEG-TPZ for enhanced theranostics.

Graphical abstract: Tumor-microenvironment-responsive poly-prodrug encapsulated semiconducting polymer nanosystem for phototherapy-boosted chemotherapy
Communication

Hexagonal boron nitride nanophotonics: a record-breaking material for the ultraviolet and visible spectral ranges

A global trend towards miniaturization and multiwavelength performance of nanophotonics drives research on novel phenomena as well as surveys for high-refractive index and strongly anisotropic materials and metasurfaces, where hBN has a central role.

Graphical abstract: Hexagonal boron nitride nanophotonics: a record-breaking material for the ultraviolet and visible spectral ranges
Communication

Selective spectral absorption of nanofibers for color-preserving daytime radiative cooling

The color-preserving daytime radiative cooling can be achieved by selective spectral absorption of nanofibers.

Graphical abstract: Selective spectral absorption of nanofibers for color-preserving daytime radiative cooling
Paper

Liquid-based cationic ligand engineering in one-dimensional bismuth bromide perovskites: A-site influence on scintillation properties

Low-dimensional bismuth-based hybrid organic–inorganic halide perovskites (Bi-HOIPs) are intriguing scintillating materials due to their anisotropic nature.

Graphical abstract: Liquid-based cationic ligand engineering in one-dimensional bismuth bromide perovskites: A-site influence on scintillation properties
Paper

How is CO2 hydrogenated to ethanol on metal–organic framework HKUST-1? Microscopic insights from density-functional theory calculations

Through DFT calculations, we quantitatively and explicitly elucidate the fundamental mechanism involved in CO2 hydrogenation to ethanol on HKUST-1.

Graphical abstract: How is CO2 hydrogenated to ethanol on metal–organic framework HKUST-1? Microscopic insights from density-functional theory calculations
Paper

Enhanced three-photon absorption excited at near-infrared laser pulses and stability of MAPbBr3 quantum dots encapsulated in mesoporous single MOF-5 crystals

The composite material MAPbBr3@MOF-5 exhibits not only significantly enhanced stability but also superior nonlinear optical properties under near-infrared laser pulse excitation.

Graphical abstract: Enhanced three-photon absorption excited at near-infrared laser pulses and stability of MAPbBr3 quantum dots encapsulated in mesoporous single MOF-5 crystals
Open Access Paper

High-throughput computation and machine learning screening of van der Waals heterostructures for Z-scheme photocatalysis

We identify 62 Z-scheme heterostructures with excellent photocatalytic performance from 11 935 hetero-bilayer structures using high-throughput calculations and machine learning.

Graphical abstract: High-throughput computation and machine learning screening of van der Waals heterostructures for Z-scheme photocatalysis
From the themed collection: Journal of Materials Chemistry A HOT Papers
Paper

Highly conductive PANI/ATMP/AgNO3 composite hydrogel electrodes for all-hydrogel-state supercapacitors

Highly conductive PANI/ATMP/AgNO3 composite hydrogel electrodes for flexible high energy density supercapacitors.

Graphical abstract: Highly conductive PANI/ATMP/AgNO3 composite hydrogel electrodes for all-hydrogel-state supercapacitors
Paper

In vivo transplantation of intrahepatic cholangiocyte organoids with decellularized liver-derived hydrogels supports hepatic cellular proliferation and differentiation in chronic liver injury

Liver-based hydrogel transplanted hepatocyte and cholangiocyte organoids as an efficient cell source and therapy for renewal of hepatocytes, angiogenesis, restoration of hepatocyte functions and resolution of liver injury.

Graphical abstract: In vivo transplantation of intrahepatic cholangiocyte organoids with decellularized liver-derived hydrogels supports hepatic cellular proliferation and differentiation in chronic liver injury
Paper

In situ analysis of a boron-based catalytic electrode with trace platinum for efficient hydrogen evolution in a wide pH range

An efficient Pt-NiB@NF catalytic electrode is rapidly constructed by mild electroless plating and electroplating. It demonstrates long-term stability at industrial-scale current densities in neutral high-salt media and alkaline systems.

Graphical abstract: In situ analysis of a boron-based catalytic electrode with trace platinum for efficient hydrogen evolution in a wide pH range
Open Access Paper

Low CO2 mass transfer promotes methanol and formaldehyde electrosynthesis on cobalt phthalocyanine

The ratio (R) of the production rates of CH3OH and CO from electrocatalytic CO2 reduction on Co phthalocyanine is related to the average CO2 mass-transfer rate (ν) by a power function (R = 0.97ν0.78).

Graphical abstract: Low CO2 mass transfer promotes methanol and formaldehyde electrosynthesis on cobalt phthalocyanine
Open Access Paper

A cradle-to-cradle approach for successive upcycling of polyethylene to polymer electrolytes to organic acids

We demonstrate the post-synthetic conversion of polyethylene into functional polymer electrolytes for lithium-ion batteries. To avoid end-of-life polymer electrolytes contributing to polymer waste, we further upcycle them into useful organic acids.

Graphical abstract: A cradle-to-cradle approach for successive upcycling of polyethylene to polymer electrolytes to organic acids
Open Access Paper

Competition between CH4 hydrate formation and phase separation in a wetted metal–organic framework MIL-101 at moderate subcooling: molecular insights into CH4 storage

Systematic molecular dynamics simulations reveal the competition between CH4 hydrate formation and phase separation of CH4 in a mesoporous metal–organic framework MIL-101 at moderate subcooling.

Graphical abstract: Competition between CH4 hydrate formation and phase separation in a wetted metal–organic framework MIL-101 at moderate subcooling: molecular insights into CH4 storage
Paper

All-inorganic copper-halide perovskites for large-Stokes shift and ten-nanosecond-emission scintillators

Demonstration of how rational design affects self-trapped emission characteristics and scintillation properties in mechanochemically synthesised caesium copper halide perovskites.

Graphical abstract: All-inorganic copper-halide perovskites for large-Stokes shift and ten-nanosecond-emission scintillators
Paper

Selective grafting of phosphorus onto Ti3C2Tx MXene enables a two-proton process and enhanced charge storage

Phosphorus atoms are selectively doped onto Ti3C2Tx MXene, leading to solely P–O doped species, which serve as new active sites to enable two-proton bonding/debonding process to boost charge storage ability of MXene.

Graphical abstract: Selective grafting of phosphorus onto Ti3C2Tx MXene enables a two-proton process and enhanced charge storage
Paper

Enhanced moisture sorption through regulated MIL-101(Cr) synthesis and its integration onto heat exchangers

Through regulated and less toxic MIL-101(Cr) synthesis and superabsorbent polymeric binders, this work reports MIL-101(Cr)-coated heat exchangers with twice the water uptake of the silica gel-coated control towards energy-efficient cooling.

Graphical abstract: Enhanced moisture sorption through regulated MIL-101(Cr) synthesis and its integration onto heat exchangers
Paper

Thermal conductivity of sliding bilayer h-BN and its manipulation with strain and layer confinement

The AC′ structure with B–B stacking exhibits a lower κ value due to the softer optical phonon modes. The strain further decreases κ by modulating the anharmonic phonon scattering.

Graphical abstract: Thermal conductivity of sliding bilayer h-BN and its manipulation with strain and layer confinement
Paper

Flexible Bi2Te3/PEDOT nanowire sandwich-like films towards high-performance wearable cross-plane thermoelectric generator and temperature sensor array

Flexible Bi2Te3/PEDOT nanowire sandwich-like films with a zT of 0.27 were fabricated for cross-plane wearable thermoelectric generation and thermal mapping.

Graphical abstract: Flexible Bi2Te3/PEDOT nanowire sandwich-like films towards high-performance wearable cross-plane thermoelectric generator and temperature sensor array
Paper

Cellulose-complexing strategy induced surface regulation towards ultrahigh utilization rate of Zn

A cellulose-complexing strategy is developed for zinc electrolytes to achieve dendrite-free Zn anodes with ultrahigh Zn utilization rate, driving the development of a robust artificial SEI fabrication method via a dissolution–regeneration mechanism.

Graphical abstract: Cellulose-complexing strategy induced surface regulation towards ultrahigh utilization rate of Zn
Paper

Low-temperature pyrolysis enables FeNi3 nanoparticle implanted N-doped carbon nanosheets as an efficient bifunctional electrocatalyst for overall water splitting

The electrocatalyst FeNi3/NCS was prepared via the low-temperature pyrolysis of the melamine tube@FeNi-LDH heterostructure, which delivered impressive activity and stability towards water splitting with a low cell potential of 1.53 V at 10 mA cm−2.

Graphical abstract: Low-temperature pyrolysis enables FeNi3 nanoparticle implanted N-doped carbon nanosheets as an efficient bifunctional electrocatalyst for overall water splitting
Paper

Local microenvironment tuning induces switching between electrochemical CO2 reduction pathways

We show that the pore size of the gas-diffusion layer used in electrochemical CO2 reduction affects CO2 mass transport. This directly influences the local reaction microenvironment, controlling the selectivity between CO and formate on Ag catalysts.

Graphical abstract: Local microenvironment tuning induces switching between electrochemical CO2 reduction pathways
Paper

Tunable properties and composition of ZnO films supported on metal surfaces

The composition, electronic structure, and chemical properties of ZnOxHy films can be engineered by the choice of underlying metal support.

Graphical abstract: Tunable properties and composition of ZnO films supported on metal surfaces
Paper

Side-chain engineering of self-doped conjugated polyelectrolytes for organic electrochemical transistors

Varied-length conjugated polyelectrolytes (2–5 methylene units) containing CPDT-alt-BT were synthesized to study the optical, electrochemical, and morphological properties. These were used in accumulation mode organic electrochemical transistors.

Graphical abstract: Side-chain engineering of self-doped conjugated polyelectrolytes for organic electrochemical transistors
Paper

Molten salt synthesis of a highly crystalline graphitic carbon nitride homojunction from a deep eutectic solvent for selective photocatalytic oxidation

A highly crystalline graphitic carbon nitride homojunction was synthesized by calcination of deep eutectic solvent precursors in NaCl/KCl molten salt media and exhibited excellent performance in selective photocatalytic oxidation.

Graphical abstract: Molten salt synthesis of a highly crystalline graphitic carbon nitride homojunction from a deep eutectic solvent for selective photocatalytic oxidation
Paper

Low-voltage organic single-crystal field-effect transistors and inverters enabled by a solution processable high-k dielectric

Low-voltage OFETs with excellent mobility, steep subthreshold swing, and low operating voltage were achieved simultaneously based on a novel solution-processable high-k dielectric.

Graphical abstract: Low-voltage organic single-crystal field-effect transistors and inverters enabled by a solution processable high-k dielectric
Paper

Gelatin methacryloyl hydrogel as an injectable scaffold with multi-therapeutic effects to promote antimicrobial disinfection and angiogenesis for regenerative endodontics

Regenerative endodontics represents a paradigm shift in dental pulp therapy for necrotic young permanent teeth.

Graphical abstract: Gelatin methacryloyl hydrogel as an injectable scaffold with multi-therapeutic effects to promote antimicrobial disinfection and angiogenesis for regenerative endodontics
Open Access Paper

Enhanced thermoelectric performance in Bi0.5Sb1.5Te3/SiC composites prepared by low-temperature liquid phase sintering

A low-temperature liquid phase sintering method combined with post heat treatment was employed to prepare p-type Bi0.5Sb1.5Te3/SiC composites with enhanced thermoelectric properties.

Graphical abstract: Enhanced thermoelectric performance in Bi0.5Sb1.5Te3/SiC composites prepared by low-temperature liquid phase sintering
Paper

MXene-decorated flexible Al2O3/TiO2 nanofibrous mats with self-adaptive stress dispersion towards multifunctional desalination

A flexible Al2O3/TiO2 nanofibrous mat with a 2.18 MPa tensile strength has been created by stress dispersion method for 2D and 3D evaporators. The evaporator has an ultrahigh solar-to-vapor efficiency of 116% and ensures 10 h without salt buildup.

Graphical abstract: MXene-decorated flexible Al2O3/TiO2 nanofibrous mats with self-adaptive stress dispersion towards multifunctional desalination
41 items

About this collection

To mark the visit of Deputy Editor Geraldine Hay to the National University of Singapore in July 2025, this web collection features recent popular articles published in Materials HorizonsJournal of Materials Chemistry A, Journal of Materials Chemistry BJournal of Materials Chemistry C and Materials Advances by authors based in the National University of Singapore.

Congratulations to all of the authors whose articles have been featured!

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