Supramolecular assembly of platinum-containing polyhedral oligomeric silsesquioxanes: an interplay of intermolecular interactions and a correlation between structural modifications and morphological transformations

Abstract

A series of alkynylplatinum(II) terpyridine complexes functionalized with polyhedral oligomeric silsesquioxane (POSS) moieties has been demonstrated to exhibit drastic color changes and give various distinctive nanostructures with interesting multi-stage morphological transformations from spheres to nanoplates in response to solvent conditions through the interplay of various intermolecular interactions, including hydrophilic–hydrophilic, hydrophobic–hydrophobic, Pt⋯Pt and π–π stacking interactions. These supramolecular architectures can be systematically modified and controlled through the molecular design and the variation of solvent compositions. In particular, drastic changes in color in response to solvent polarity were observed through the incorporation of the charged moieties, representing a new class of potential candidates for functional materials with sensing or imaging capabilities. This class of complexes has been studied by ¹H NMR spectroscopy, electron microscopy, UV-vis absorption and emission spectroscopy.