Issue 89, 2019
From the journal:

Chemical Communications

Highly stereoselective intramolecular Buchner reaction of diazoacetamides catalyzed by a Ru(ii)–Pheox complex†

Nga Phan Thi Thanh, ORCID logo a   Masaya Tone,a   Hayato Inoue,a   Ikuhide Fujisawaa  and  Seiji Iwasa ORCID logo *a  

* Corresponding authors

a Department of Applied Chemistry and Life Science, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi, Aichi 441-8580, Japan
E-mail: iwasa@chem.tut.ac.jp

Abstract

This work reports the first efficient enantioselective intramolecular Buchner reaction of diazoacetamides. The Ru(II)–Pheox catalyst was shown to be highly efficient in this transformation in terms of both the regio- and enantioselectivity (up to 99% ee) giving the desired products in quantitative yield.

Graphical abstract: Highly stereoselective intramolecular Buchner reaction of diazoacetamides catalyzed by a Ru(ii)–Pheox complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C9CC06889A
Article type
Communication
Submitted
04 9 2019
Accepted
09 10 2019
First published
10 10 2019

Chem. Commun., 2019,55, 13398-13401

Permissions

Request permissions

Highly stereoselective intramolecular Buchner reaction of diazoacetamides catalyzed by a Ru(II)–Pheox complex

N. Phan Thi Thanh, M. Tone, H. Inoue, I. Fujisawa and S. Iwasa, Chem. Commun., 2019, 55, 13398 DOI: 10.1039/C9CC06889A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements