Network design for soft materials: addressing elasticity and fracture resistance challenges

Abstract

Soft materials, such as elastomers and gels, feature crosslinked polymer chains that provide stretchable and elastic mechanical properties. These properties are derived from entropic elasticity, which limits energy dissipation and makes the material susceptible to fracture. To address this issue, network designs that dissipate energy through the plastic zone have been introduced to enhance toughness; however, this approach compromises elasticity, preventing the material from fully recovering its original shape after deformation. In this review, we describe the trade-off between fracture resistance and elasticity, exploring network designs that overcome this limitation to achieve both high toughness and low hysteresis. The development of soft materials that are both elastic and fracture-resistant holds significant promise for applications in stretchable electronics, soft robotics, and biomedical devices. By analyzing successful network designs, we identify strategies to further improve these materials and discuss potential enhancements based on existing limitations.