Alkynide and acetonitrile activation by strained AlPC2 heterocycles

Steffi Roters; Alexander Hepp; J. Chris Slootweg; Koop Lammertsma; Werner Uhl

doi:10.1039/C2CC33300G

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Alkynide and acetonitrile activation by strained AlPC₂ heterocycles†‡

Steffi Roters,^a Alexander Hepp,^a J. Chris Slootweg,^b Koop Lammertsma*^b and Werner Uhl*^a

Author affiliations

* Corresponding authors

^a Institut für Anorganische und Analytische Chemie der Westfälischen Wilhelms-Universität Münster, Corrensstraße 30, D-48149 Münster, Germany
E-mail: uhlw@uni-muenster.de

^b Department of Chemistry and Pharmaceutical Sciences, VU University Amsterdam, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands
E-mail: k.lammertsma@vu.nl

Abstract

Bicyclic compounds with annulated four- (AlPC₂) and five-membered (P₂C₃) rings activate and capture Al-alkynides and acetonitrile at room temperature to afford bicyclic compounds with unique six-membered Al₂PC₃ and AlNPC₃ heterocycles.

This article is part of the themed collection: Frontiers in Molecular Main Group Chemistry

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Article information

DOI: https://doi.org/10.1039/C2CC33300G
Article type: Communication
Submitted: 08 Maijs 2012
Accepted: 03 Aug. 2012
First published: 07 Aug. 2012

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Chem. Commun., 2012,48, 9616-9618

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Alkynide and acetonitrile activation by strained AlPC₂ heterocycles

S. Roters, A. Hepp, J. C. Slootweg, K. Lammertsma and W. Uhl, Chem. Commun., 2012, 48, 9616 DOI: 10.1039/C2CC33300G

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