NiCo2O4-based materials for electrochemical supercapacitors

Abstract

Nickel cobaltite (NiCo₂O₄), with excellent electrochemical performance, has become a new class of energy storage material for electrochemical supercapacitors, which facilitates to relieve the pressure of energy crisis and environmental pollution. It possesses richer electroactive sites and at least two magnitudes higher electrical conductivity than that of NiO and Co₃O₄, which exhibit not only large power density, but also high energy density of up to 35 W h kg⁻¹. Furthermore, it shows comparable capacitive performances with noble metal oxides of RuO₂, but with much lower cost and more abundant resources. This feature article briefly analyses the energy storage mechanism of NiCo₂O₄, summarizes the methodologies and nanostructures discovered in recent years, and points out the potential problems and future prospects of utilizing NiCo₂O₄-based materials as supercapacitor electrodes. Moreover, composite electrodes based on nickel cobaltite are also elaborated with considerable interest. Since the pioneering work of Hu and his group in 2010, numerous research studies have also demonstrated NiCo₂O₄ electrodes to show remarkable supercapacitive performances; however, more specialized work should be performed to further develop the potential of this novel electrode material so as to realize their massive commercial applications.