Nanocolumnar 1-dimensional TiO2 photoanodes deposited by PVD-OAD for perovskite solar cell fabrication

Abstract

Perovskite solar cells have attracted increasing interest among the photovoltaic community in the last few years owing to their unique properties and high efficiency. In the present work, we report the fabrication of perovskite solar cells based on highly ordered 1-dimensional porous TiO₂ photoanodes, which are uniform on a large area. These nanocolumnar porous TiO₂ photoanodes were deposited by physical vapor deposition in an oblique angle configuration (PVD-OAD) by varying the zenithal angle between the target and the substrate normal. Perovskite infiltration into these 1-dimensional nanocolumnar structures was homogeneous through the entire thickness of the porous layer as revealed by secondary ion mass spectroscopy studies. The fabricated solar cells, with an optimized thickness of the photoanode and with industrially accepted methods, will pave the way for easy implementation on a large scale.