A ruthenium tellurocarbonyl (CTe) complex with a cyclopentadienyl ligand: systematic studies of a series of chalcogenocarbonyl complexes [CpRuCl(CE)(H2IMes)] (E = O, S, Se, Te)

Ayumi Suzuki; Takahiro Arai; Kota Ikenaga; Yuichiro Mutoh; Noriko Tsuchida; Shinichi Saito; Youichi Ishii

doi:10.1039/C6DT04440A

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A ruthenium tellurocarbonyl (CTe) complex with a cyclopentadienyl ligand: systematic studies of a series of chalcogenocarbonyl complexes [CpRuCl(CE)(H₂IMes)] (E = O, S, Se, Te)†

Ayumi Suzuki,^a Takahiro Arai,^b Kota Ikenaga,^b Yuichiro Mutoh,

*^a Noriko Tsuchida,^c Shinichi Saito*^a and Youichi Ishii*^b

Author affiliations

* Corresponding authors

^a Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan
E-mail: ymutoh@rs.tus.ac.jp, ssaito@rs.kagu.tus.ac.jp

^b Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-3-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan
E-mail: yo-ishii@kc.chuo-u.ac.jp

^c Department of Liberal Arts, Faculty of Medicine, Saitama Medical University, 38 Morohongo, Moroyama-machi, Iruma-gun, Saitama 350-0495, Japan

Abstract

The first tellurocarbonyl complex with a half-sandwich structure [CpRuCl(CTe)(H₂IMes)] was synthesized by a ligand substitution reaction. The practically complete series of the CpCE complexes [CpRuCl(CE)(H₂IMes)] (E = O, S, Se, Te) were systematically explored. The tellurium atom in the CTe complex could be smoothly replaced with lighter chalcogen atoms.

This article is part of the themed collection: Selenium & Tellurium chemistry at the beginning of the 3rd millennium: a celebration of ICCST

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Article information

DOI: https://doi.org/10.1039/C6DT04440A
Article type: Communication
Submitted: 23 Nov. 2016
Accepted: 24 Nov. 2016
First published: 24 Nov. 2016

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Dalton Trans., 2017,46, 44-48

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A ruthenium tellurocarbonyl (CTe) complex with a cyclopentadienyl ligand: systematic studies of a series of chalcogenocarbonyl complexes [CpRuCl(CE)(H₂IMes)] (E = O, S, Se, Te)

A. Suzuki, T. Arai, K. Ikenaga, Y. Mutoh, N. Tsuchida, S. Saito and Y. Ishii, Dalton Trans., 2017, 46, 44 DOI: 10.1039/C6DT04440A

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Dalton Transactions