Issue 10, 2019
From the journal:

Dalton Transactions

Effect of substituents on molybdenum triiodide complexes bearing PNP-type pincer ligands toward catalytic nitrogen fixation†

Takayuki Itabashi,a   Ikki Mori,a   Kazuya Arashiba,a   Aya Eizawa, ORCID logo a   Kazunari Nakajima ORCID logo b  and  Yoshiaki Nishibayashi ORCID logo *a  

* Corresponding authors

a Department of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
E-mail: ynishiba@sys.t.u-tokyo.ac.jp

b Frontier Research Centre for Energy and Resources, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

Abstract

Molybdenum triiodide complexes bearing various substituted pyridine-based PNP-type pincer ligands are prepared and characterized by X-ray analysis. Their catalytic activity is investigated toward the reduction of nitrogen gas into ammonia under ambient reaction conditions.

Graphical abstract: Effect of substituents on molybdenum triiodide complexes bearing PNP-type pincer ligands toward catalytic nitrogen fixation

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Article information

DOI
https://doi.org/10.1039/C8DT04975K
Article type
Communication
Submitted
18 Dec. 2018
Accepted
21 Janv. 2019
First published
21 Janv. 2019

Dalton Trans., 2019,48, 3182-3186

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Effect of substituents on molybdenum triiodide complexes bearing PNP-type pincer ligands toward catalytic nitrogen fixation

T. Itabashi, I. Mori, K. Arashiba, A. Eizawa, K. Nakajima and Y. Nishibayashi, Dalton Trans., 2019, 48, 3182 DOI: 10.1039/C8DT04975K

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