The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative†
Takahiro
Sasamori 
*b
and
Norihiro
Tokitoh
ac
*b
and
Norihiro
Tokitoh
ac
Abstract
A stable 1,4-disilabenzene was generated from the reaction of a stable disilyne with 3-hexyne. Its photochemical isomerization afforded the corresponding disilabenzvalene, which was structurally characterized by a single-crystal X-ray diffraction analysis.
- This article is part of the themed collection: Inorganic chemistry of the p-block elements
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