Reduction of carbon dioxide on photoexcited nanoparticles of VIII group metals

Abstract

The photocatalytic reduction of carbon dioxide on nanoparticles of group VIII transition metals represents an emerging research area in recent years because of their promise in transforming carbon dioxide, a greenhouse gas, into value-added chemicals and fuels with the energy input of light. This mini review summarizes the fundamentals of the reduction of carbon dioxide and addresses how the photoexcitation of the metal nanoparticles can influence the reactions. The important roles of non-thermal hot electrons and photothermal effect in the photocatalytic reduction of carbon dioxide are highlighted, and the recent research reported in the literature are overviewed. There are still challenges in characterizing the photocatalytic reactions to distinguish the contributions of non-thermal and photothermal effects.