Issue 34, 2021
From the journal:

CrystEngComm

Two isomeric zeolite-like metal–organic frameworks with mechanically responsive luminescence emission and gas adsorption properties†

Shuang Peng,‡a   Yan-Jie Qi,‡a   Xin-Hao Li,b   Cai Sun, ORCID logo a   Ling-Yun Li, ORCID logo b   Xin-Xiong Li, ORCID logo *a   Shou-Tian Zheng ORCID logo a  and  Qichun Zhang ORCID logo *cd  

* Corresponding authors

a State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
E-mail: lxx@fzu.edu.cn

b Key Laboratory of Eco-materials Advanced Technology, College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350108, China

c School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, Singapore
E-mail: qczhang@ntu.edu.sg

d Center of Super-Diamond and Advanced Films (COSDAF), City University of Hong Kong, Hong Kong, SAR 999077, P. R. China

Abstract

Two isomeric zeolite-like metal–organic frameworks with the formula of [(CH3)2NH2][Cd(TPO)]·xsolvent were successfully prepared and characterized. Both frameworks are constructed from tetrahedral TPO3− nodes and tetrahedrally connected Cd2+ nodes, representing rare examples of zeolite-like MOFs with an isomeric characteristic. Moreover, one of the frameworks shows mechanically responsive luminescence emission after the crystals are ground for different times. Additionally, it has permanent porosity, and can selectively adsorb CO2 over N2.

Graphical abstract: Two isomeric zeolite-like metal–organic frameworks with mechanically responsive luminescence emission and gas adsorption properties

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Article information

DOI
https://doi.org/10.1039/D1CE00464F
Article type
Communication
Submitted
07 Apr. 2021
Accepted
12 Maijs 2021
First published
13 Maijs 2021

CrystEngComm, 2021,23, 5753-5757

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Two isomeric zeolite-like metal–organic frameworks with mechanically responsive luminescence emission and gas adsorption properties

S. Peng, Y. Qi, X. Li, C. Sun, L. Li, X. Li, S. Zheng and Q. Zhang, CrystEngComm, 2021, 23, 5753 DOI: 10.1039/D1CE00464F

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