Ba3[Al(PO4)3]: rational design of a promising deep-UV transparent SHG crystal with balanced overall performance originating from the condensation of quartz-type [Al(PO4)4]9− units

Zhi Fang; Chun-Li Hu; Bing-Ping Yang; Jiang-Gao Mao

doi:10.1039/D0TC05743F

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Ba₃[Al(PO₄)₃]: rational design of a promising deep-UV transparent SHG crystal with balanced overall performance originating from the condensation of quartz-type [Al(PO₄)₄]⁹⁻ units†

Zhi Fang,

^a Chun-Li Hu,^a Bing-Ping Yang

^a and Jiang-Gao Mao

*^a

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* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
E-mail: mjg@fjirsm.ac.cn

Abstract

A new SHG material, Ba₃[Al(PO₄)₃], has been rationally designed by expanding the anionic condensation design strategy from atom-sharing to anionic-group-sharing. As the first Ba₃[B(PO₄)₃]-type acentric phosphate, Ba₃[Al(PO₄)₃] is characterized by moderate second-order optical nonlinearity, beneficial type I phase-matching behavior, deep-UV transparency and high thermal stability, favourable for practical applications.

This article is part of the themed collection: Journal of Materials Chemistry C HOT Papers

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Article information

DOI: https://doi.org/10.1039/D0TC05743F
Article type: Communication
Submitted: 07 Dec. 2020
Accepted: 24 Dec. 2020
First published: 24 Dec. 2020

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J. Mater. Chem. C, 2021,9, 1550-1554

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Ba₃[Al(PO₄)₃]: rational design of a promising deep-UV transparent SHG crystal with balanced overall performance originating from the condensation of quartz-type [Al(PO₄)₄]⁹⁻ units

Z. Fang, C. Hu, B. Yang and J. Mao, J. Mater. Chem. C, 2021, 9, 1550 DOI: 10.1039/D0TC05743F

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Journal of Materials Chemistry C