Issue 4, 2024
From the journal:

Chemical Communications

MOF (UiO-66-NH2)@COF (TFP–TABQ) hybrids via on-surface condensation reactions for sustainable energy storage†

Dawid Pakulski,*ab   Verónica Montes-García, ORCID logo c   Włodzimierz Czepa,d   Dawid Marcinkowski,d   Haijun Peng,c   Tomasz Chudziak,d   Adam Gorczyński, ORCID logo d   Wojciech Kukułka,c   Cataldo Valentini, ORCID logo a   Violetta Patroniak, ORCID logo d   Paolo Samorì ORCID logo *c  and  Artur Ciesielski ORCID logo *ac  

* Corresponding authors

a Centre for Advanced Technologies, Adam Mickiewicz University, Uniwersytetu Poznańskiego 10, Poznań 61-614, Poland
E-mail: dawid.pakulski@amu.edu.pl

b Adam Mickiewicz University Foundation, Poznań Science and Technology Park, Rubież 46, Poznań 61-612, Poland

c Université de Strasbourg, CNRS, ISIS 8 allée Gaspard Monge, Strasbourg 67000, France
E-mail: samori@unistra.fr, ciesielski@unistra.fr

d Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznańskiego 8, Poznań 61-614, Poland

Abstract

Core–shell MOF@COF hybrids were synthesized via subsequent modification of MOF UiO-66-NH2 with 1,3,5-triformylphloroglucinol (TFP) and 2,3,5,6-tetraaminobenzoquinone (TABQ). The hybrids exhibited significant surface area (236 m2 g−1) and outstanding electrochemical performance (103 F g−1 at 0.5 A g−1), surpassing both COFs and MOFs, thereby showcasing the potential of on-surface condensation reactions for developing high-performance energy storage devices.

Graphical abstract: MOF (UiO-66-NH2)@COF (TFP–TABQ) hybrids via on-surface condensation reactions for sustainable energy storage

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Article information

DOI
https://doi.org/10.1039/D3CC05187K
Article type
Communication
Submitted
21 Okt. 2023
Accepted
30 Nov. 2023
First published
01 Dec. 2023

Chem. Commun., 2024,60, 412-415

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MOF (UiO-66-NH2)@COF (TFP–TABQ) hybrids via on-surface condensation reactions for sustainable energy storage

D. Pakulski, V. Montes-García, W. Czepa, D. Marcinkowski, H. Peng, T. Chudziak, A. Gorczyński, W. Kukułka, C. Valentini, V. Patroniak, P. Samorì and A. Ciesielski, Chem. Commun., 2024, 60, 412 DOI: 10.1039/D3CC05187K

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