Issue 20, 2000
From the journal:

Chemical Communications

Synthesis and characterization of the monomer Ga{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6): a low valent gallium(i) carbene analogue

Ned J. Hardman,a   Barrett E. Eichlera  and  Philip P. Power*a  

* Corresponding authors

a Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California, USA.
E-mail: E-mail: pppower@ucdavis.edu

Abstract

The reaction between solvent free Li{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6), ‘GaI’ and potassium in toluene afforded Ga{(NDippCMe)2CH} 1 which features a V-shaped, two-coordinate, six-electron gallium(I) center electronically analogous to a singlet carbene carbon.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B005686N
Article type
Communication
Submitted
12 Jūl. 2000
Accepted
06 Sept. 2000
First published
27 Sept. 2000

Chem. Commun., 2000, 1991-1992

Permissions

Request permissions

Synthesis and characterization of the monomer Ga{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6): a low valent gallium(I) carbene analogue

N. J. Hardman, B. E. Eichler and P. P. Power, Chem. Commun., 2000, 1991 DOI: 10.1039/B005686N

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements