Dissociative cycloelimination, a new selenium based pericyclic reaction

Lars Henriksen; Søren Jakobsen

doi:10.1039/B107688B

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Dissociative

Lars Henriksen*^a and Søren Jakobsen^a

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* Corresponding authors

^a Department of Chemistry, University of Copenhagen, Universitetsparken 5, Copenhagen, Denmark.
E-mail: larsh@kiku.dk

Abstract

The stereospecific oxidation of hydrazine into cis-diimide and the catalytic disproportionation of hydrogen peroxide effected by selenoxides are suggested to involve a dissociative cycloelimination from an intermediary selenurane.

This article is part of the themed collection: Selenium & Tellurium chemistry at the beginning of the 3rd millennium: a celebration of ICCST

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Article information

DOI: https://doi.org/10.1039/B107688B
Article type: Communication
Submitted: 24 Aug. 2001
Accepted: 19 Okt. 2001
First published: 13 Nov. 2001

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Chem. Commun., 2001, 2448-2449

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