Issue 12, 2002
From the journal:

Chemical Communications

Formation of [Ar*Ge[upper bond 1 start]{CH2C(Me)C(Me)C[upper bond 1 end]H2}CH2C(Me)[double bond, length as m-dash]]2 (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-i-Pr3) via reaction of Ar*GeGeAr* with 2,3-dimethyl-1,3-butadiene: evidence for the existence of a germanium analogue of an alkyne

Matthias Stender,a   Andrew D. Phillipsa  and  Philip P. Power*a  

* Corresponding authors

a Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California, USA
E-mail: pppower@ucdavis.edu

Abstract

The reduction of Ar*GeCl (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-i-Pr3) with one equivalent of potassium leads to the formation of a germanium analogue of an alkyne Ar*GeGeAr* 1; reaction of 1 with 2,3-dimethyl-1,3-butadiene yields [Ar*Ge[upper bond 1 start]{CH2C(Me)C(Me)C[upper bond 1 end]H2}CH2C(Me)[double bond, length as m-dash]]22, which was structurally characterized.

Graphical abstract: Formation of [Ar*Ge [[upper bond 1 start]] {CH2C(Me)C(Me)C [[upper bond 1 end]] H2}CH2C(Me) [[double bond, length as m-dash]] ]2 (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-i-Pr3) via reaction of Ar*GeGeAr* with 2,3-dimethyl-1,3-butadiene: evidence for the existence of a germanium analogue of an alkyne

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Article information

DOI
https://doi.org/10.1039/B203403D
Article type
Communication
Submitted
09 Apr. 2002
Accepted
09 Maijs 2002
First published
20 Maijs 2002

Chem. Commun., 2002, 1312-1313

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Formation of [Ar*Ge[upper bond 1 start]{CH2C(Me)C(Me)C[upper bond 1 end]H2}CH2C(Me)[double bond, length as m-dash]]2 (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-i-Pr3) via reaction of Ar*GeGeAr* with 2,3-dimethyl-1,3-butadiene: evidence for the existence of a germanium analogue of an alkyne

M. Stender, A. D. Phillips and P. P. Power, Chem. Commun., 2002, 1312 DOI: 10.1039/B203403D

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