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Abstract | Cited by

The complex cation ligand [Ru(pytpy)2]2+ (pytpy = 4′-(4-pyridyl)-2,2′∶6′,2″-terpyridine) is an expanded 4,4′-bipyridine; we describe the first example of a coordination polymer in which [Ru(pytpy)2]2+ plays the role of a bridging bidentate ligand.

Graphical abstract: The first example of a coordination polymer from the expanded 4,4′-bipyridine ligand [Ru(pytpy)2]2+ (pytpy = 4′-(4-pyridyl)-2,2′∶6′,2″-terpyridine)

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