Issue 3, 2009

SFM study of the surface of halogen-bonded hybrid co-crystals containing long-chain perfluorocarbons

Abstract

Different scanning force microscopy (SFM) techniques were employed to investigate the structure and composition of the fundamental crystal faces of prototype halogen-bonded co-crystals of long-chain perfluorocarbons. These crystals were found to show surfaces with well-defined ledges formed by intersecting crystal planes having different chemical compositions with the perfluorocarbons (PFCs) covering the largest area of the crystal as a reminiscence of the strong segregation observed in the bulk crystal structure.

Graphical abstract: SFM study of the surface of halogen-bonded hybrid co-crystals containing long-chain perfluorocarbons

Supplementary files

Article information

Article type
Paper
Submitted
26 Aug. 2008
Accepted
21 Nov. 2008
First published
22 Dec. 2008

CrystEngComm, 2009,11, 510-515

SFM study of the surface of halogen-bonded hybrid co-crystals containing long-chain perfluorocarbons

G. Maruccio, V. Arima, R. Cingolani, R. Liantonio, T. Pilati, R. Rinaldi and P. Metrangolo, CrystEngComm, 2009, 11, 510 DOI: 10.1039/B815816A

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