A new anionic metal–organic framework showing tunable emission by lanthanide(III) doping and highly selective CO2 adsorption properties

Rong-Ying Chen; Dan Tian; Yun-Wu Li; Ying-Bin Lv; Hong-Wei Sun; Ze Chang; Xian-He Bu

doi:10.1039/C5RA02935J

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A new anionic metal–organic framework showing tunable emission by lanthanide(III) doping and highly selective CO₂ adsorption properties†

Rong-Ying Chen,^a Dan Tian,^a Yun-Wu Li,^a Ying-Bin Lv,^a Hong-Wei Sun,^a Ze Chang*^a and Xian-He Bu^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, TKL of Metal- and Molecule-Based Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, P. R. China
E-mail: changze@nankai.edu.cn

Abstract

A new three-dimensional porous metal–organic framework, {[NH₂(CH₃)₂][Zn(atz)(ox)]·H₂O}_n (1) (Hatz = 5-amino-1H-tetrazole, H₂ox = oxalic acid), has been solvothermally synthesized and characterized by elemental analysis, IR, TG, and single-crystal X-ray diffraction analysis. Complex 1 exhibits an anionic framework that can be simplified as a rarely reported 4-connected lon network. Complex 1 could be utilized as a platform for emission tuning by doping different lanthanide ions. In addition, gas adsorption studies reveal that 1 has a high isosteric heat of CO₂ and good adsorption selectivity for CO₂ over CH₄ and N₂.

This article is part of the themed collection: RSC Advances Editors' collection: f Block Chemistry

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Article information

DOI: https://doi.org/10.1039/C5RA02935J
Article type: Paper
Submitted: 15 Febr. 2015
Accepted: 27 Febr. 2015
First published: 27 Febr. 2015

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RSC Adv., 2015,5, 24655-24660

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A new anionic metal–organic framework showing tunable emission by lanthanide(III) doping and highly selective CO₂ adsorption properties

R. Chen, D. Tian, Y. Li, Y. Lv, H. Sun, Z. Chang and X. Bu, RSC Adv., 2015, 5, 24655 DOI: 10.1039/C5RA02935J

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