Issue 5, 2017
From the journal:

Chemical Communications

Cyclotrimerisation of isocyanates catalysed by low-coordinate Mn(ii) and Fe(ii) m-terphenyl complexes†

Helen R. Sharpe,a   Ana M. Geer,a   Huw E. L. Williams,b   Toby J. Blundell,a   William Lewis, ORCID logo a   Alexander J. Blake ORCID logo a  and  Deborah L. Kays ORCID logo *a  

* Corresponding authors

a School of Chemistry, University of Nottingham, University Park, Nottingham, UK
E-mail: Deborah.Kays@nottingham.ac.uk

b Centre for Biomolecular Sciences, University of Nottingham, University Park, Nottingham, UK

Abstract

Two- and three-coordinate m-terphenyl complexes of manganese and iron are efficient catalysts for the selective cyclotrimerisation of primary aliphatic isocyanates affording isocyanurates in short reaction times and under mild conditions.

Graphical abstract: Cyclotrimerisation of isocyanates catalysed by low-coordinate Mn(ii) and Fe(ii) m-terphenyl complexes

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Article information

DOI
https://doi.org/10.1039/C6CC07243G
Article type
Communication
Submitted
05 Sept. 2016
Accepted
16 Dec. 2016
First published
16 Dec. 2016

Chem. Commun., 2017,53, 937-940

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Cyclotrimerisation of isocyanates catalysed by low-coordinate Mn(II) and Fe(II) m-terphenyl complexes

H. R. Sharpe, A. M. Geer, H. E. L. Williams, T. J. Blundell, W. Lewis, A. J. Blake and D. L. Kays, Chem. Commun., 2017, 53, 937 DOI: 10.1039/C6CC07243G

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