A bipyridiyl–oxazoline cobalt catalyst tBuBPOCoCl2 has been developed for the Markovnikov selective hydroboration of alkenes using pinacolborane and NaOtBu as the in situ activator with up to >98 : 2 branched : linear selectivity (24 examples, 45–92% isolated yield).
J. Peng, J. H. Docherty, A. P. Dominey and S. P. Thomas, Chem. Commun., 2017, 53, 4726 DOI: 10.1039/C7CC01085K
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