Molecular recognition and solvatomorphism of a cyclic peptoid: formation of a stable 1D porous framework†
Eleonora
Macedi, 
a
Alessandra
Meli,
a
Francesco
De Riccardis,
a
Patrizia
Rossi,
b
Vincent J.
Smith,
c
Leonard J.
Barbour,
c
Irene
Izzo
*a
and
Consiglia
Tedesco
*a
a
Alessandra
Meli,
a
Francesco
De Riccardis,
a
Patrizia
Rossi,
b
Vincent J.
Smith,
c
Leonard J.
Barbour,
c
Irene
Izzo
*a
and
Consiglia
Tedesco
*a
Abstract
Molecular recognition and the hydrophobic effect explain the solvatomorphic behavior of a hexameric α-cyclic peptoid. Either a pure non-porous crystal form or a stable one-dimensional porous framework is obtained using an appropriate choice of crystallization solvents.
- This article is part of the themed collection: Host‒Guest chemistry: in honour of Luigi Nassimbeni’s 9th decade
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