Visible light-induced water splitting in an aqueous suspension of a plasmonic Au/TiO2 photocatalyst with metal co-catalysts

Abstract

We found that plasmonic Au particles on titanium(IV) oxide (TiO₂) act as a visible-light-driven photocatalyst for overall water splitting free from any additives. This is the first report showing that surface plasmon resonance (SPR) in a suspension system effectively induces overall water splitting. Modification with various types of metal nanoparticles as co-catalysts enhanced the evolution of H₂ and O₂. Among these, Ni-modified Au/TiO₂ exhibited 5-times higher rates of H₂ and O₂ evolution than those of Ni-free Au/TiO₂. We succeeded in designing a novel solar energy conversion system including three elemental technologies, charge separation with light harvest and an active site for O₂ evolution (plasmonic Au particles), charge transfer from Au to the active site for H₂ production (TiO₂), and an active site for H₂ production (Ni cocatalyst), by taking advantage of a technique for fabricating size-controlled Au and Ni nanoparticles. Water splitting occurred in aqueous suspensions of Ni-modified Au/TiO₂ even under irradiation of light through an R-62 filter.