Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework

Hannes Depauw; Irena Nevjestić; Guangbo Wang; Karen Leus; Freddy Callens; Els De Canck; Klaartje De Buysser; Henk Vrielinck; Pascal Van Der Voort

doi:10.1039/C7TA08103K

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Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework†

Hannes Depauw,^a Irena Nevjestić,

^b Guangbo Wang,^a Karen Leus,

^a Freddy Callens,

^b Els De Canck,^a Klaartje De Buysser,

^a Henk Vrielinck

^b and Pascal Van Der Voort

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Ghent University, Krijgslaan 281-S3, B-9000 Belgium
E-mail: Pascal.vandervoort@ugent.be
Tel: +32-9-264-4442

^b Department of Solid State Sciences, Ghent University, Krijgslaan 281-S1, B-9000 Belgium

Abstract

A new series of bimetallic COMOC-2(V)/DUT-5(Al) frameworks are developed and fully characterized. Electron paramagnetic resonance and transmission electron microscopy confirm the homogeneous dispersion of Al/V in the entire framework. The study of the flexibility by means of CO₂ pressure dependent XRPD and high pressure sorption reveals the co-existence of two different large pore phases and a narrow pore phase in the entire pressure regime.

This article is part of the themed collection: 2017 Journal of Materials Chemistry A HOT Papers

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DOI: https://doi.org/10.1039/C7TA08103K
Article type: Communication
Submitted: 14 Sept. 2017
Accepted: 17 Okt. 2017
First published: 18 Okt. 2017

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J. Mater. Chem. A, 2017,5, 24580-24584

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Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework

H. Depauw, I. Nevjestić, G. Wang, K. Leus, F. Callens, E. De Canck, K. De Buysser, H. Vrielinck and P. Van Der Voort, J. Mater. Chem. A, 2017, 5, 24580 DOI: 10.1039/C7TA08103K

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Journal of Materials Chemistry A

Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework†

Abstract

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Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework

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