A solution-processable dissymmetric porous organic cage

A. G. Slater; M. A. Little; M. E. Briggs; K. E. Jelfs; A. I. Cooper

doi:10.1039/C7ME00090A

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A solution-processable dissymmetric porous organic cage†

A. G. Slater,

*^a M. A. Little,

^a M. E. Briggs,

^a K. E. Jelfs

^b and A. I. Cooper

Author affiliations

* Corresponding authors

^a Department of Chemistry and Materials Innovation Factory, University of Liverpool, Crown Street, Liverpool, UK
E-mail: anna.slater@liverpool.ac.uk

^b Department of Chemistry, Imperial College London, South Kensington, London SW7 2AZ, UK

Abstract

Two dissymmetric racemic analogues of the chiral porous organic cage, CC3, were isolated and unambiguously characterised as a racemate pair of the R,R,R,S,S,S and S,S,S,R,R,R-diastereomers (CC3-RS and CC3-SR). CC3-RS/CC3-SR equals the highest porosity measured for CC3 but is an order of magnitude more soluble, making it an excellent candidate for incorporation into a membrane for separation applications.

This article is part of the themed collections: In memory of Paul O’Brien, Celebrating Excellence in Research: 100 Women of Chemistry, 2018 MSDE Hot Articles and MSDE Emerging Investigators 2018

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DOI: https://doi.org/10.1039/C7ME00090A
Article type: Paper
Submitted: 04 Sept. 2017
Accepted: 09 Okt. 2017
First published: 22 Nov. 2017
This article is Open Access

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Mol. Syst. Des. Eng., 2018,3, 223-227

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A solution-processable dissymmetric porous organic cage

A. G. Slater, M. A. Little, M. E. Briggs, K. E. Jelfs and A. I. Cooper, Mol. Syst. Des. Eng., 2018, 3, 223 DOI: 10.1039/C7ME00090A

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Molecular Systems Design & Engineering

A solution-processable dissymmetric porous organic cage†

Abstract

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A solution-processable dissymmetric porous organic cage

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