Preparation of MoS2/TiO2 based nanocomposites for photocatalysis and rechargeable batteries: progress, challenges, and perspective

Abstract

The rapidly increasing severity of the energy crisis and environmental degradation are stimulating the rapid development of photocatalysts and rechargeable lithium/sodium ion batteries. In particular, MoS₂/TiO₂ based nanocomposites show great potential and have been widely studied in the areas of both photocatalysis and rechargeable lithium/sodium ion batteries due to their superior combination properties. In addition to the low-cost, abundance, and high chemical stability of both MoS₂ and TiO₂, MoS₂/TiO₂ composites also show complementary advantages. These include the strong optical absorption of TiO₂vs. the high catalytic activity of MoS₂, which is promising for photocatalysis; and excellent safety and superior structural stability of TiO₂vs. the high theoretic specific capacity and unique layered structure of MoS₂, thus, these composites are exciting as anode materials. In this review, we first summarize the recent progress in MoS₂/TiO₂-based nanomaterials for applications in photocatalysis and rechargeable batteries. We highlight the synthesis, structure and mechanism of MoS₂/TiO₂-based nanomaterials. Then, advancements and strategies for improving the performance of these composites in photocatalytic degradation, hydrogen evolution, CO₂ reduction, LIBs and SIBs are critically discussed. Finally, perspectives on existing challenges and probable opportunities for future exploration of MoS₂/TiO₂-based composites towards photocatalysis and rechargeable batteries are presented. We believe the present review would provide enriched information for a deeper understanding of MoS₂/TiO₂ composites and open avenues for the rational design of MoS₂/TiO₂ based composites for energy and environment-related applications.