Hybrid organic–inorganic mononuclear lanthanoid single ion magnets†
Walter
Cañón-Mancisidor, 
*ab
Patricio
Hermosilla-Ibáñez,
ab
Diego
Venegas-Yazigi
ab
and
Guillermo
Mínguez Espallargas
*d
*ab
Patricio
Hermosilla-Ibáñez,
ab
Diego
Venegas-Yazigi
ab
and
Guillermo
Mínguez Espallargas
*d
Abstract
The first family of hybrid mononuclear organic–inorganic lanthanoid complexes is reported, based on [PW11O39]7− and 1,10-phenanthroline ligands. This hybrid approach causes a dramatic improvement of the relaxation time (×1000) with a decrease of the optimal field while maintaining the Ueff of the inorganic analogues.
- This article is part of the themed collection: Celebrating Latin American Talent in Chemistry
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