A decanuclear [DyIII6ZnII4] cluster: a {ZnII4} rectangle surrounding an octahedral {DyIII6} single molecule magnet

Nikoleta Stavgianoudaki; Milosz Siczek; Tadeusz Lis; Giulia Lorusso; Marco Evangelisti; Constantinos J. Milios

doi:10.1039/C9DT00440H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A decanuclear [Dy ^III₆Zn ^II₄] cluster: a {Zn ^II₄} rectangle surrounding an octahedral {Dy ^III₆} single molecule magnet†

Nikoleta Stavgianoudaki,^a Milosz Siczek,

^b Tadeusz Lis,^b Giulia Lorusso,

^c Marco Evangelisti

^c and Constantinos J. Milios

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, The University of Crete, Voutes 71003, Herakleion, Greece
E-mail: komil@uoc.gr

^b Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, Wroclaw 50-383, Poland

^c Instituto de Ciencia de Materiales de Aragón (ICMA), CSIC – Universidad de Zaragoza, 50009 Zaragoza, Spain

Abstract

An octahedral {Dy^III₆} cage within a diamagnetic {Zn^II₄} rectangle is reported, with magnetic relaxation studies revealing single-molecule magnet behaviour for the complex under zero external dc field with U_eff = 43 K and τ_o = 1 × 10⁻⁵ s.

This article is part of the themed collection: Spotlight Collection focused on Inorganic Chemistry in Greece

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C9DT00440H
Article type: Communication
Submitted: 30 Janv. 2019
Accepted: 18 Febr. 2019
First published: 18 Febr. 2019
This article is Open Access

Download Citation

Dalton Trans., 2019,48, 3566-3570

Permissions

Request permissions

A decanuclear [Dy^III₆Zn^II₄] cluster: a {Zn^II₄} rectangle surrounding an octahedral {Dy^III₆} single molecule magnet

N. Stavgianoudaki, M. Siczek, T. Lis, G. Lorusso, M. Evangelisti and C. J. Milios, Dalton Trans., 2019, 48, 3566 DOI: 10.1039/C9DT00440H

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions