Removal of chromium(vi) from polluted wastewater by chemical modification of silica gel with 4-acetyl-3-hydroxyaniline

Abstract

In the current study, a new adsorbent that is insoluble in water and many acid solutions and has a high adsorption capacity for Cr(VI) metal ions was synthesized. In the synthesis process, 3-chloropropyl-trimethoxysilane (CPTS) was first modified on a silica gel (Si) surface. Secondly, 4-acetyl-3-hydroxyaniline (AHAP) was immobilized on the modified silica gel compound (Si-CPTS). As a result of the immobilization process, a new adsorbent compound named Si-CPTS-AHAP (silica gel-3-chloropropyltrimethoxy silane 4-acetyl-3-hydroxyaniline) was obtained, which was used to separate Cr(VI) ions from aqueous solution (K₂Cr₂O₇) and industrial wastewater. The material was characterized using scanning electron microscopy and Fourier-transform infrared spectroscopy. The amount of chromium adsorbed was detected by ultraviolet-visible spectroscopy. The adsorption was evaluated using batch methods. The effects of temperature, pH, concentration, adsorbent amount and interaction time on the adsorption of Si-CPTS-AHAP were also investigated. The adsorption of Cr(VI) ions on Si-CPTS-AHAP was investigated via adsorption kinetics, isotherm and thermodynamic studies. The value of the isotherm parameters and the highest adsorption yields were calculated from the Dubinin–Radushkevich, Freundlich and Langmuir isotherm equations. Thermodynamic features such as entropy (ΔS), enthalpy (ΔH) and free energy (ΔG) were also calculated from the experimental results. The experimental results showed that the best recoveries of Cr(VI) metal ions are under the conditions of 180 min (interaction time), 0.05 g (adsorbent amount) and 323.15 K (temperature) at pH 2. Si-CPTS-AHAP can be used for the removal of poisonous pollutants in wastewater.