Platinum complexes of a boron-rich diphosphine ligand

Abstract

Herein, we describe the preparation, characterization, and reactivity of two Pt^II bis-hydrocarbyl complexes containing the 1,2-bis(di(3-dicyclohexylboraneyl)propylphosphino)ethane (P₂B^Cy₄) ligand. These scaffolds are readily accessed from four-fold hydroboration of 1,2-bis(diallylphosphino)ethane Pt^II precursors. The electrophilcity of such frameworks is showcased by facile coordination of the strong Lewis base, 4-N,N-dimethylaminopyridine (DMAP). Thermolysis reactions of [Pt(P₂B^Cy₄)(R)₂] (R = CH₃ or Ph) show enhanced (and divergent) reactivity when compared to their “all-alkyl” diphosphine counterparts, implicating involvement of the pendant borane groups. This behaviour is attenuated by protection of these units with DMAP.