Red-shifted backbone N–H photocaging agents†
Mark D.
Distefano 
b
and
Zachary T.
Ball
*a
b
and
Zachary T.
Ball
*a
Abstract
Light is a uniquely powerful tool for spatiotemporal control of molecular structure, necessitating the development of new photocaging approaches. This communication describes the design, synthesis, and reactivity of two new photoreactive boronic acid reagents for backbone N–H modification and subsequent photocleavage.
- This article is part of the themed collection: Methodology development for protein modifications
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