Advances in photochemical and electrochemical incorporation of sulfur dioxide for the synthesis of value-added compounds

Abstract

Organic photochemistry and electrochemistry currently receive tremendous attention in organic synthesis as both techniques enable the reagent-less activation of organic molecules without using expensive and hazardous redox reagents. The incorporation of SO₂ into organic molecules is a relatively modern research topic, which likewise gains immense popularity since the discovery of the SO₂ surrogate DABSO. Sulfur-containing organic molecules are omnipresent in pharmaceuticals and agrochemicals. This review covers the recent progress in electrochemical and photochemical methodologies for the incorporation and uses of SO₂ in the synthesis of value-added compounds. Additionally, different work techniques are demonstrated for the synthetic application of SO₂.