Selectivity of hosts for guests by liquid-assisted grinding: differences between solution and mechanochemistry

Jean Lombard; Heinrich Laker; Francis Prins; Helene Wahl; Tanya le Roex; Delia A. Haynes

doi:10.1039/D1CE01286J

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Selectivity of hosts for guests by liquid-assisted grinding: differences between solution and mechanochemistry†

Jean Lombard,

^a Heinrich Laker,

^a Francis Prins,^a Helene Wahl,

^a Tanya le Roex

^a and Delia A. Haynes

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry & Polymer Science, Stellenbosch University, P. Bag X1, Matieland, South Africa
E-mail: dhaynes@sun.ac.za

Abstract

Selectivity for particular guests in two host–guest systems has been investigated using both solution-based and mechanochemical methods. Selectivity was shown to occur in both systems when using mechanochemistry. The selectivity profile obtained using mechanochemistry can be different from that observed when carrying out analogous selectivity experiments in solution.

This article is part of the themed collections: Crystal Engineering in Africa, Host‒Guest chemistry: in honour of Luigi Nassimbeni’s 9th decade and Crystal Engineering Techniques

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DOI: https://doi.org/10.1039/D1CE01286J
Article type: Communication
Submitted: 24 Sept. 2021
Accepted: 30 Sept. 2021
First published: 06 Okt. 2021
This article is Open Access

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CrystEngComm, 2021,23, 7380-7384

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Selectivity of hosts for guests by liquid-assisted grinding: differences between solution and mechanochemistry

J. Lombard, H. Laker, F. Prins, H. Wahl, T. le Roex and D. A. Haynes, CrystEngComm, 2021, 23, 7380 DOI: 10.1039/D1CE01286J

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Selectivity of hosts for guests by liquid-assisted grinding: differences between solution and mechanochemistry†

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Selectivity of hosts for guests by liquid-assisted grinding: differences between solution and mechanochemistry

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