Self-assembled Janus plasmene nanosheets as flexible 2D photocatalysts

Abstract

A leaf is a free-standing photocatalytic system that can effectively harvest solar energy and convert CO₂ and H₂O into carbohydrates in a continuous manner without the need for regeneration or tedious product extraction steps. Despite encouraging advances achieved in designing artificial photocatalysts, most of them function in bulk solution or on rigid surfaces. Here, we report on a 2D flexible photocatalytic system based on close packed Janus plasmene nanosheets. One side of the Janus nanosheets is hydrophilic with catalytically active palladium, while the opposite side is hydrophobic with plasmonic nanocrystals. Such a unique design ensures a stable nanostructure on a flexible polymer substrate, preventing dissolution/degradation of plasmonic photocatalysts during chemical conversion in aqueous solutions. Using catalytic reduction of 4-nitrophenol as a model reaction, we demonstrated efficient plasmon-enhanced photochemical conversion on our flexible Janus plasmene. The photocatalytic efficiency could be tuned by adjusting the palladium thickness or types of constituent building blocks or their orientations, indicating the potential for tailor-made catalyst design for desired reactions. Furthermore, the flexible Janus plasmene nanosheets were designed into a small 3D printed artificial tree, which could continuously convert 30 mL of chemicals in 45 minutes.