Formaldehyde recognition through aminal formation in a luminescent metal–organic framework

Jia-Li Li; Xiao Xiong; Dong Luo; Yu-Bai Wei; Weigang Lu; Dan Li

doi:10.1039/D2CC02041F

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Formaldehyde recognition through aminal formation in a luminescent metal–organic framework†

Jia-Li Li,

^a Xiao Xiong,

^a Dong Luo,

^a Yu-Bai Wei,^a Weigang Lu

*^a and Dan Li

*^a

Author affiliations

* Corresponding authors

^a College of Chemistry and Materials Science, and Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, P. R. China
E-mail: weiganglu@jnu.edu.cn, danli@jnu.edu.cn

Abstract

Two isostructural pillar-layer MOFs (JNU-105 and JNU-105-(NH₂)₂) have been successfully synthesized. JNU-105-(NH₂)₂ exhibits a red-shifted luminescence “turn on” for formaldehyde without the interference from other VOCs and a detection limit of 1.87 ppb. In situ single-crystal transformation studies confirm the aminal formation on the pillar linker, which was attributed to the exclusive luminescence response toward formaldehyde.

This article is part of the themed collection: Emerging Trends in MOFs

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Article information

DOI: https://doi.org/10.1039/D2CC02041F
Article type: Communication
Submitted: 10 Apr. 2022
Accepted: 03 Maijs 2022
First published: 03 Maijs 2022

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Chem. Commun., 2022,58, 6490-6493

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Formaldehyde recognition through aminal formation in a luminescent metal–organic framework

J. Li, X. Xiong, D. Luo, Y. Wei, W. Lu and D. Li, Chem. Commun., 2022, 58, 6490 DOI: 10.1039/D2CC02041F

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Chemical Communications

Formaldehyde recognition through aminal formation in a luminescent metal–organic framework†

Abstract

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Formaldehyde recognition through aminal formation in a luminescent metal–organic framework

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