Marine waste upcycling—recovery of nylon monomers from fishing net waste using seashell waste-derived catalysts in a CO2-mediated thermocatalytic process

Abstract

A lot of fishing nets have been abandoned, lost, or discarded at sea. Herein, we aimed at applying seashell waste-derived catalytic materials to a thermocatalytic process to recover a valuable commodity chemical (e.g., caprolactam) from fishing net waste (FNW) made of polyamide 6. For catalyst synthesis, seashell waste was carbonized in N₂ and CO₂ environments (denoted as SSWC-N₂ and SSWC-CO₂, respectively); here, the basicity of SSWC-CO₂ was two-fold more than that of SSWC-N₂. The thermocatalytic conversion of FNW was also conducted under N₂ and CO₂ atmospheres. Using SSWC-CO₂ in the thermocatalytic conversion conducted under a CO₂ atmosphere maximized the caprolactam recovery (80 wt% of FNW feedstock, the highest yield reported to date) possibly because the base-catalyzed decomposition of polyamide 6 was enhanced by more reactive cleavage of the amide linkage in CO₂. SSWC-CO₂ was reused for at least three cycles. In conclusion, SSWC-CO₂ is a promising alternative catalyst to recover caprolactam from FNW. The findings from this study offer insights into developing a new thermocatalytic upcycling process for marine waste such as FNW and seashell waste. This aids in reducing microplastic pollution and increasing economic potential for marine waste valorization.