Selective electrochemical CO2 conversion with a hybrid polyoxometalate

Satoshi Kuramochi; Jamie M. Cameron; Tomoya Fukui; Kieran D. Jones; Stephen P. Argent; Shinpei Kusaka; Ryo Shiraishi; Yusuke Tamaki; Taiki Yatsu; Takuya Shiga; Osamu Ishitani; Hiroki Oshio; Graham N. Newton

doi:10.1039/D3CC02138F

Selective electrochemical CO₂ conversion with a hybrid polyoxometalate†

Satoshi Kuramochi,^a Jamie M. Cameron,

^b Tomoya Fukui,

^a Kieran D. Jones,

^b Stephen P. Argent,

^c Shinpei Kusaka,

^a Ryo Shiraishi,^a Yusuke Tamaki,^d Taiki Yatsu,^d Takuya Shiga,

^a Osamu Ishitani,

^de Hiroki Oshio

*^a and Graham N. Newton

*^b

Author affiliations

* Corresponding authors

^a Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennoudai 1-1-1, Tsukuba, Ibaraki, Japan
E-mail: oshio@chem.tsukuba.ac.jp

^b GSK Carbon Neutral Laboratories for Sustainable Chemistry, School of Chemistry, University of Nottingham, Nottingham, UK
E-mail: graham.newton@nottingham.ac.uk

^c School of Chemistry, University of Nottingham, Nottingham, UK

^d Department of Chemistry, School of Science, Tokyo Institute of Technology, O-okayama, meguro-ku, Tokyo, Japan

^e Department of Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, Hiroshima 739 8526, Japan

Abstract

A multi-component coordination compound, in which ruthenium antenna complexes are connected to a polyoxotungstate core is presented. This hybrid cluster effectively promotes the electrochemical conversion of CO₂ to C1 feedstocks, the selectivity of which can be controlled by the acidity of the media.

This article is part of the themed collection: 2023 Pioneering Investigators

Chemical Communications

Selective electrochemical CO₂ conversion with a hybrid polyoxometalate†

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