Low-concentration CO2 capture using metal–organic frameworks – current status and future perspectives

Abstract

The ever-increasing atmospheric CO₂ level is considered to be the major cause of climate change. Although the move away from fossil fuel-based energy generation to sustainable energy sources would significantly reduce the release of CO₂ into the atmosphere, it will most probably take time to be fully implemented on a global scale. On the other hand, capturing CO₂ from emission sources or directly from the atmosphere are robust approaches that can reduce the atmospheric CO₂ concentration in a relatively short time. Here, we provide a perspective on the recent development of metal–organic framework (MOF)-based solid sorbents that have been investigated for application in CO₂ capture from low-concentration (<10 000 ppm) CO₂ sources. We summarized the different sorbent engineering approaches adopted by researchers, both from the sorbent development and processing viewpoints. We also discuss the immediate challenges of using MOF-based CO₂ sorbents for low-concentration CO₂ capture. MOF-based materials, with tuneable pore properties and tailorable surface chemistry, and ease of handling, certainly deserve continued development into low-cost, efficient CO₂ sorbents for low-concentration CO₂ capture.